Check out 'Nonheme binuclear transition metal complexes with hydrosulfide and polychalcogenides' New from Amit Majumdar and co. at Indian Association for the Cultivation of Science Amit Majumdar buff.ly/3wjUt0E

When do persulfides transfer a persulfide group to a thiol and when do they release H2S? Our collab w/ PA Champagne in J. Am. Chem. Soc. provides new experimental & computational insights. Great work Kaylin & Jyoti on working out this chemistry! pubs.acs.org/doi/10.1021/ja…

Generation of Thiosulfate, Selenite, Dithiosulfite, Perthionitrite, Nitric Oxide, and Reactive Chalcogen Species by Binuclear Zinc(II)-Chalcogenolato/-Polychalcogenido Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac…

Generation of Thiosulfate, Selenite, Dithiosulfite, Perthionitrite, Nitric Oxide, and Reactive Chalcogen Species by Binuclear Zinc(II)-Chalcogenolato/-Polychalcogenido Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Majumdar and co-workers Inorganic Chemistry #zinc #chalcogens

The delivery partner is not answering my phone and it shows delivery in 10 minutes for the last 1.5 hours. I suspect he stole my order and swiggy is refusing to refund my order. I want a full refund also with compensation for wasting my time. #harshamjty #Swiggy

Reduction of Nitrite in an Iron(II)-Nitrito Compound by Thiols and Selenol Produces Dinitrosyl Iron Complexes via an {FeNO}7 Intermediate | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac…

Another one from the Que lab. 5,000-fold increase in the HAT with Pyrazoles. Que lab journey from N4Py to N2Py2Pz in PNAS. Thank you Marcel and Alex Guo UMN Department of Chemistry PNASNews #larryQue pnas.org/doi/10.1073/pn…

And here's the final published version of the paper: The Enemark-Feltham formalism at 50: An interview with John Enemark and a personal reflection. Do repost! Comments are welcome here and by email! #nitrosyl doi.org/10.1016/j.jino…

Functional Nonheme Diiron(II) Complexes Catalyze the Direct Reduction of Nitrite to Nitric Oxide in Relevance to the Diiron Protein YtfE | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac…

Functional Nonheme Diiron(II) Complexes Catalyze the Direct Reduction of Nitrite to Nitric Oxide in Relevance to the Diiron Protein YtfE | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Majumdar and co-workers Inorganic Chemistry #iron #nitrite #reductase #NO #YtfE #nonheme

Our Work on Nitric Oxide: Thiocarboxylate and Acid Chloride Mediated Generation of Nitric Oxide from a Dinickel(II)-Bis(ONO) Complex Involving the Formation of Perthionitrite and O-Nitrosyl Carboxylate | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

New Inorganic Chemistry paper: Mo/W-CO complexes + S₈ → COS! Highlights links between CO & reactive S species (Se behaves differently!) Initial 2023 ChemRxiv preprint, now w COS quantification & new insights. Great work Toby, Haley & Keyan! Haley Smith Keyan Li pubs.acs.org/doi/10.1021/ac…

⭐️New paper⭐️ Fe-S clusters aren't just NO sensors- direct reduction of nitrite to NO! We've isolated and characterized a thiolate supported mononitrosylated Fe₄S₄ cluster that undergoes facile nitrosylation. pubs.acs.org/doi/10.1021/ja… #chemistry #bioinorganic #NOsignaling

Check out our Inorganic Chemistry paper on Fe-NO formation from Fe(II) w/ SSNO(-) & SNO(-)! New insights into metal nitrosyl & reactive sulfur species formation from small S/N hybrid molecules. Great work Keyan (@Keyanl10), Juan, and George! pubs.acs.org/doi/10.1021/ac…

Second-Sphere Interaction Allows Selective Reduction of Nitrite to NO or Ammonia by Synthetic Iron Porphyrins | Journal of the American Chemical Society Congratulations, Sudip and Paramita Saha pubs.acs.org/doi/full/10.10…

Another contribution from our research group on the catalytic reduction of nitrite: A Mononitrosyl Diiron(II) Compound Catalyzes the Reduction of Nitrite to Nitric Oxide | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac…

New Chem Commun paper on Cys-activated H2Se delivery from isoselenocyanates. Includes mechanistic insights, solution characterization, and cell imaging. Great work Reis, Keyan, Christopher, Arman, Turner, & Kaylin! pubs.rsc.org/en/content/art…

🎃🎃Happy Halloween from the Pluth Lab! 🦇🦇

Our work on the interactions of nitrite and polychalcogenides in the presence of Fe(II): Unraveling the General Trend of the Reaction of Nitrite with Diiron(II)-polychalcogenides | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

Hydrogen cyanide (HCN) is the newest gasotransmitter & a key protic small molecule bioregulator. We developed a platform approach to develop & deploy biocompatible responsive chemical tools for HCN delivery. Check out Mike's paper in Angewandte Chemie! onlinelibrary.wiley.com/doi/10.1002/an…