A curious case of truncated [1.1.1]propellane oligomerization demonstrates that selective one-pot [2]staffane formation becomes possible with either SF5Cl or CF3SF4Cl through radical polarity matching. Thanks to Beilstein JOC for the invited manuscript! beilstein-journals.org/bjoc/articles/…

Azorellolide! How can you not work on a natural product that starts with "Azo"? Great collaboration with Tantillo Lab. I have to say my respect for carbocations has enormously gown through this project. They are just too high in energy and have too many options. But you can tame

Biomimetic Synthesis of Azorellolide via Cyclopropylcarbinyl Cation Chemistry | Journal of the American Chemical Society Penn Dirk H. Trauner Tantillo Lab UC Davis Department of Chemistry #Biomimetic #Azorellolide #Cyclopropylcarbinyl #Cation Total Synthesis Total Synthesis and Methodology Highlights pubs.acs.org/doi/10.1021/ja…

Biomimetic Synthesis of Azorellolide via Cyclopropylcarbinyl Cation Chemistry pubs.acs.org/doi/full/10.10…

Assembly of the Tricyclic Core of Alopecurone C by Asymmetric Donor/Donor Carbene C–H Insertion pubs.acs.org/doi/full/10.10…

Cytotoxic Stilbenoids, Hetero- and Homodimers of Homoisoflavonoids from Prospero autumnale pubs.acs.org/doi/full/10.10…

Post-Transition State Bifurcation Leading to Diradical & Zwitterionic Intermediates: Controlling Nonstatistical Kinetic Selectivity via Solvent Effects | Journal of the American Chemical Society UW-Madison Chemistry UW–Madison UC Davis Department of Chemistry UC Davis pubs.acs.org/doi/10.1021/ja…

Synthetically Relevant Post-Transition State Bifurcation Leading to Diradical and Zwitterionic Intermediates: Controlling Nonstatistical Kinetic Selectivity through Solvent Effects pubs.acs.org/doi/10.1021/ja…

Vibrationally Assisted Tunneling through the Bread of a Proton Sandwich─Connections to Dynamic Matching | Journal of the American Chemical Society UC Davis UC Davis Department of Chemistry Gabe Gomes Carnegie Mellon University the gomes group pubs.acs.org/doi/10.1021/ja…

Vibrationally Assisted Tunneling through the Bread of a Proton Sandwich─Connections to Dynamic Matching pubs.acs.org/doi/full/10.10…

Efficient and modular synthesis of ibogaine and related alkaloids nature.com/articles/s4155…

Characterization and Engineering of a Bisabolene Synthase Reveal an Unusual Hydride Shift and Key Residues Critical for Mono-, Bi-, and Tricyclic Sesquiterpenes Formation | Journal of the American Chemical Society Tantillo Lab UC Davis Department of Chemistry Peking University pubs.acs.org/doi/10.1021/ja…

Characterization and Engineering of a Bisabolene Synthase Reveal an Unusual Hydride Shift and Key Residues Critical for Mono-, Bi-, and Tricyclic Sesquiterpenes Formation pubs.acs.org/doi/10.1021/ja…

Convenient synthesis and antiproliferative activity of 2-(Indol-2-yl)-2-arylacetamides sciencedirect.com/science/articl…

Avoidance of Secondary Carbocations, Unusual Deprotonation, and Nonstatistical Dynamic Effects in the Cyclization Mechanism of Tetraisoquinane | Journal of the American Chemical Society UC Davis UC Davis Research Tantillo Lab FLORIDA pubs.acs.org/doi/10.1021/ja…

Avoidance of Secondary Carbocations, Unusual Deprotonation, and Nonstatistical Dynamic Effects in the Cyclization Mechanism of Tetraisoquinane pubs.acs.org/doi/10.1021/ja…

Structure Elucidation, Biosynthetic Gene Cluster Distribution, and Biological Activities of Ketomemicin Analogs in Salinispora mdpi.com/1660-3397/23/3…

Diazacyclobutenes as Reactive Intermediates: The Cascade Cyclization of Thiolated Ene-ynes and Azodicarboxylates to Provide Tetrahydroindoles pubs.acs.org/doi/abs/10.102…

Dynamically controlled kinetic selectivity in reactions promoted by transition metal catalysts cell.com/chem-catalysis…

PeriRxn, a Tool for Assessing Pericyclicity through Nucleus-Independent Chemical Shifts and Normalized Multicenter Bond Orders pubs.acs.org/doi/full/10.10…