Development of a new method for synthesizing α-aminocarbonyls from abundant C(sp3)-rich raw materials in a single step, which can be applied to array-type library synthesis. J. Am. Chem. Soc. by J. Liu and Prof. Matthew Gaunt The Gaunt Group unuboreya.blogspot.com/2024/09/catch-… #synthesis

Successful N2 activation using Co-Mg and Co-Ca trinuclear complexes. N2 activation is also possible with alkaline earth metals (Mg, Ca) with NH3 production. SynOpen Journal by Dr. A. G. Bakhoda et al. unuboreya.blogspot.com/2024/09/catch-… #N2activation #NH3production #economy

Development of a novel radical addition/aldol reaction cascade led to the first total synthesis of Ganoapplanin containing five contiguous stereocenters. J. Am. Chem. Soc. by Prof. Dr. Thomas Magauer The Magauer Lab unuboreya.blogspot.com/2024/09/catch-… #totavsynthesis #oxidation #latestage

A new method for synthesizing nitroolefins using triflyl nitrate has been established with a wide range of substrates, high yields, regioselectivity, easy operation and safety. J Org Chem/Org Lett by G. S. Reddy and Prof. E. J. Corey unuboreya.blogspot.com/2024/09/catch-… #nitrate #regioselective

Stereoselective synthesis of boron compounds with complex 3D structures was achieved by a sequential reaction of 1,2-metallate rearrangement/anti-SN2' elimination/cycloaddition. SYNLETT Journal by Prof. V. K. Aggarwal Varinder Aggarwal 🇺🇦🇺🇦🇺🇦 et al. unuboreya.blogspot.com/2024/09/catch-… #boron

Sb-centered tripodal ligand with a quinolyl donor ligand was synthesized, and complex formed with RhCl3 in which the Rh(I) center is stabilized by the donation of Sb to the Z-type ligand. Organometallics by Prof. F. P. Gabbaï Francois Gabbai et al. unuboreya.blogspot.com/2024/09/catch-… #Sb #Rh

An efficient one-pot synthesis method for 1,2,3,4,5-Pentacarbomethoxy-cyclopentadiene has been developed with significantly improving yield, reaction time, and safety, and making. SYNTHESIS Journal by Prof. T. H. Lambert et al. unuboreya.blogspot.com/2024/09/catch-… #onepot #synthesis #economy

Cationic Bi(III)-catalyzed allylic C-H functionalization of olefins has been developed, providing the first direct evidence of Bi-olefin interactions. J. Am. Chem. Soc. by Prof. C. Lichtenberg Assoc. Prof. Yi-Ming Wang et al. unuboreya.blogspot.com/2024/09/catch-… #bismuth #allyl #mechanism

The regioselective oxidation of carbohydrates using in situ-preparable Pd-catalyzed system was developed with high efficiency and selectivity for glucosides. SYNLETT Journal by Prof. Dr. M. D. Witte and Prof. Dr. A. J. Minnaard et al. unuboreya.blogspot.com/2024/09/catch-… #Pd #catalysis

An efficient converting cyclopentenones to pyridones was developed with mild conditions, high regioselectivity, wide functional group tolerance, and access to 15N-labeled compounds. Angewandte Chemie by Prof. Dr. B. Morandi et al. unuboreya.blogspot.com/2024/09/catch-… #pyridone #Pharmaceuticals

The first photochemical Machetti-De Sarlo reaction was developed using a novel EDA complex as a photosensitizer, achieving a broad substrate range under practical and mild conditions. J Org Chem/Org Lett by Assoc. Prof. Dr. C. Thongsornkleeb et al. unuboreya.blogspot.com/2024/09/catch-… #Photoreaction

Development of a haloform coupling reaction applicable to primary and secondary alcohols, have enabled efficient coupling and the direct synthesis of esters with complex structures. Angewandte Chemie by Dr A. J. J. Lennox et al. unuboreya.blogspot.com/2024/09/catch-… #alcohol #ester #mechanism

Just now!!! #TECHSCALE

The #TECHSCALE conference starts today! 🚀 We are looking forward to the scientific discussions and the results of the collaboration between Univerzita Palackého, Univerzita Karlova and @Ceitec VUT v Brně. Pumera Research Group Future Energy & Innovation Lab

How wonderful stay!! #CzechRepublic #Liblice zamek-liblice.cz/cs/

An efficient synthesis for fused polycyclic systems has been developed by combining A3 coupling and intramolecular Diels-Alder reactions with achieving high structural diversity. Chemistry by Assoc. Prof. Z. Guo et al. unuboreya.blogspot.com/2024/09/catch-… #onestep #heterocycle #polycycle

Honestly, I just shared the latest research findings! #TECHSCALE

Photosensitizer-free O2(a1Δg) generation from the CT transition of the water-O2 complex of arylamine and synthesis of azo compounds via oxidative coupling reaction have been achieved. Chemical Science by Prof. T. K. Mukherjee et al. unuboreya.blogspot.com/2024/09/catch-… #amine #azo #economy

Conversion of simple norbornenes to complex 8,5,5-tricyclic lactam skeletons with high stereoselectivity and regioselectivity, providing a flexible intermediate that can be functionalized in a variety of ways J Org Chem/Org Lett by Dr J. Knowles et al. unuboreya.blogspot.com/2024/09/catch-… #lactam

Established a new synthesis method for N,N'-bis(3-pyridyl)methanediamine, succeeded in synthesizing 1,3,5,7-tetra(3-pyridyl)-1,3,5,7-tetrazacyclooctane and determining its structure. SynOpen Journal by Dr. L. Li et al. unuboreya.blogspot.com/2024/09/catch-… #synthesis #macrocycle #twist