Check out our recent paper on Gallium Hydride‐Catalyzed Selective Hydroboration of Unsaturated Organic Substrates - ChemPlusChem - Wiley Online Library …mistry-europe.onlinelibrary.wiley.com/doi/abs/10.100… NISER Sagrika Rajput ChemPlusChem Congratulations to Sagrika; thanks to all Reviewers

Gallium Hydride‐Catalyzed Selective Hydroboration of Unsaturated Organic Substrates …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/cp…

NEW WEAKLY COORDINATING ANIONS: Deprotonation of extremely bulky amines is not easy. Even superbases failed! BUT... simple addition of KOtBu to a highly reactive sila-imine gave a new WCA. More surprising acid-base and FLP reactivity is found in ChemEurJ: Chemistry - A European Journal rb.gy/nw8vsd

BENZENE(4-): Aromatic but not so stable - high charge & full antibonding orbitals! Most C6H6(4-) claims are highly controversial. We report proof for C6H6(4-) by comparing structures of Ca/Yb & Sr/Sm pairs that are normally perfectly matching Angewandte Chemie shorturl.at/glrx1

Gallium Hydride-Catalyzed Selective Hydroboration of Unsaturated Organic Substrates (Sharanappa Nembenna Sharanappa Nembenna and co-workers) onlinelibrary.wiley.com/doi/10.1002/cp…

Excited to announce that our research on acyclic monomeric aluminyl is now published in J. Am. Chem. Soc. ! Big thanks to Petra Petra Vasko for the DFT support, Simon Aldridge Group , and all my colleagues for their invaluable assistance. Grateful to DFG public | @[email protected] for funding this work!

Ga(I) CHEMISTRY: NO, NOT A TYPO! Not Ca(I)…unfortunately. We prepared a Ga(I) complex with a superbulky BDI ligand in quantitative yield and show reactivity. Look at these DIPeP protecting arms! Dedicated to Hubert Schmidbaur’s 90thbirthday @ZAAC shorturl.at/aprw0

We are very happy to share a new chapter for our low-valent Ga chemistry! Check out insitu generated, reactive (di-)gallenes just published in Nature Synthesis by first author Philipp Dabringhaus! nature.com/articles/s4416…

Also out today is a ChemRxiv preprint from Wenbang Yang describing the reductive addition of Zn–Zn bonds to main group carbene analogues. The work challenges preconceptions behind addition mechanisms, hinting that these may not always be oxidative. chemrxiv.org/engage/chemrxi…

Congratulations Henric Henric Steffenfauseweh & Dennis @Dennis_Rott on your recent work Ghadwal Group on "Non‐Kekulé m‐Quinodimethane Singlet Diradicals" another fruitful collaboration (thanks Bas) with Bas de Bruin🟥 UvA Amsterdam - DFG public | @[email protected] Humboldt-Stiftung 👉 …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ch…

Our recent article on Zinc Catalyzed Chemoselective Hydrofunctionalization of Cyanamides - now published in Chemical Communications pubs.rsc.org/en/content/art… Congratulations to Sagrika,Rajata and Nithya

Have a look our just accepted article i.e., Insights Into the Magnesium‐Catalyzed Catalyzed C‐C Coupling of Terminal Alkynes with Carbodiimides. - Mukhopadhyay - European Journal of Organic Chemistry - Wiley Online Library …mistry-europe.onlinelibrary.wiley.com/doi/abs/10.100… Congrats to Sayantan and all

Take a look at 'Zinc catalyzed chemoselective hydrofunctionalization of cyanamides' New from Sharanappa Nembenna, Sagrika Rajput, Rajata Kumar Sahoo and Nithya Thilakan 🌏 NISER pubs.rsc.org/en/content/art…

Happy to receive the Best Poster Award at RSC meet held at NISER on 11th November. Royal Society of Chemistry NISER

📢ICMGSC 2025, 13-16th February: As we approach close to the conference, here is the overview of the speakers! icmgsc2025.com IISER Thiruvananthapuram School of Chemistry IISER TVM Royal Society of Chemistry DaltonTransactions @remulveygroup Ghadwal Group Chris Slootweg Francois Gabbai DM Research Group IISERK

Welcome to ICMGSC 2025 IISER Thiruvananthapuram Royal Society of Chemistry DaltonTransactions

Deepest thanks to the organizers for providing this invaluable opportunity. Main Group Chemistry @ IISERTVM Royal Society of Chemistry #ICMGSC2025 #iisertvm

Check out our recent publication "Exploring Tetra-Coordinate Bis-Guanidinate Supported Boron Complexes: Synthesis, Characterization, and Photophysical Properties"- now published in New Journal of Chemistry pubs.rsc.org/en/content/art… NISER Sharanappa Nembenna New Journal of Chemistry

Arene Activation by Calcium Hydride/Zinc Amide Equilibration | Journal of the American Chemical Society University of Bath pubs.acs.org/doi/10.1021/ja…

Have a look our recent preprint on "Bis-Guanidinate Scaffold for the Construction of Unique Zr(IV)-Li(I) Heterobimetallic Complexes" | ChemRxiv - go.shr.lc/40Quvhi Bis-guanidinate acts as a trianionic L2X3 type