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Experimentally Delineating the Catalytic Effect of a Single Water Molecule in the Photochemical Rearrangement of the Phenylperoxy Radical to the Oxepin-2(5H)-one-5-yl Radical | JACS PRS-Group Universität Gießen #Water #Photochemical #Rearrangement #Radical pubs.acs.org/doi/10.1021/ja…

A superb line-up of invited speakers were the highlights of the Nanochemistry and Materials session 10th EuChemS Chemistry Congress - complemented by >70 short/flash talk speakers. Thank you all for your excellent contributions! PRS-Group AKRoesky [email protected] Volker Deringer KruegerResearchLab

Hydrogen Tunneling Exhibiting Unexpectedly Small Primary Kinetic Isotope Effects (Claudio M. Nunes Cláudio M. Nunes and co-workers PRS-Group) onlinelibrary.wiley.com/doi/10.1002/ch…

🏆Frank Glorius has received the Emil Fischer Medal of the GDCh at the #ORCHEM2024 conference Universität Regensburg for his work. He has championed the #catalytic asymmetric #hydrogenation of #arenes and impacted many other areas of organic #synthesis. Glorius studied chemistry

The leaching of chloride ions from polyvinyl chloride (PVC) is due primarily to quantum tunnelling, according to a surprise discovery by Tibor Szilvási and Gbolagade Olajide of the The University of Alabama. chemistryworld.com/chloride-ions-…

Contrasting Historical and Physical Perspectives in #AsymmetricCatalysis: DeltaDeltaG# versus Enantiomeric Excess (Peter R. Schreiner and co-workers) PRS-Group @tub_chem #openaccess onlinelibrary.wiley.com/doi/10.1002/an…

Congratulations Neil & team! Fun fact: Bredt was for 26 years a professor in Aachen, as successor of Claisen. His adopted daughter, Maria Lipp, became the first woman to receive a PhD in Aachen (in 1918) and later, in 1938, was Aachen’s first female professor.

Competitive Heavy-Atom Tunneling Reactions Controlled Through Electronic Effects by Claudio M. Nunes, Peter R. Schreiner, and co-workers (Cláudio M. Nunes, Universidade de Coimbra, PRS-Group, Universität Gießen) #OpenAccess Chemistry Europe onlinelibrary.wiley.com/doi/10.1002/ce…

Congratulations CNTR | Arms Control Research on the launch of the 1st issue of the CNTR Monitor at the Federal Foreign Office. The topic of #DualUse shows how important it is that experts in Natural Sciences, Technology & International Security are joined up. Excellent piece of work!

🧪 Cláudio M. Nunes & Peter R. Schriner ( PRS-Group ) discuss how electron-donating substituents can control quantum mechanical tunneling (QMT) reactivity—and why QMT deserves a place in general chemistry curricula chemistryviews.org/tuning-quantum…

We are starting the year with great news! 💡 EuChemS President Angela Agostiano has signed the IUPAC Proclamation, urging more funding for basic chemical research to tackle global challenges. 🌍🔬 Read more: euchems.eu/euchems-increa…

🧪 Cláudio M. Nunes (Universidade de Coimbra ) and Peter R. Schreiner (PRS-Group ) discuss how electron-donating substituents can control quantum mechanical tunneling (QMT) reactivity—and why QMT deserves a place in general chemistry curricula doi.org/10.1002/chemv.…

We are excited to announce the launch of Angewandte Chemie Novit - An #OpenAccess journal dedicated to elevating the most significant advances in chemistry. For more information, visit angewandte.org/novit. #AngewandteChemieNovit GDCh

The Richardson Group ETHZ group ETH Zurich have discovered a new mechanism for the reaction of triplet carbenes via nonadiabatic quantum tunnelling. A concerted pathway dominates only at very low temperatures and switches to a sequential process when heated. • onlinelibrary.wiley.com/doi/10.1002/an…

Cage Alkyl Carbenes Provide Experimental Evidence for Isotope-Controlled Selectivity in Competing Tunneling Reactions | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

Cage Alkyl Carbenes Provide Experimental Evidence for Isotope-Controlled Selectivity in Competing Tunneling Reactions | Journal of the American Chemical Society Universität Gießen Total Synthesis and Methodology Highlights pubs.acs.org/doi/10.1021/ja…

Preparation of a neutral nitrogen allotrope hexanitrogen C2h-N6  nature.com/articles/s4158…

So excited the team has made a nitrogen allotrope! Check it out here: nature.com/articles/s4158…

And when we thought we already knew all possible small molecules, N6 suddenly appears🤯 One of the most beautiful papers of the 21st century was published yesterday. nature.com/articles/s4158…

Remarkable advance in basic chemistry: Researchers created hexanitrogen, six bound nitrogen atoms. It's the most energetic molecule ever made! If it can be made & stored in bulk (big if) it could be a powerful rocket fuel or energy storage material. chemistryworld.com/news/most-ener…