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Expanding the Landscape of Phosphorous-Based Open Shell Species: Stable Mono-, Di-, and Trianionic Radicals Based on a Contorted Triphosphaalkene (Andreas Orthaber and co-workers) Orthaber Lab, SMC Program, Mohd Asif Ansari, Raj.Deka #OpenAccess onlinelibrary.wiley.com/doi/10.1002/an…

Great win streak by the team SMC Program. Mohd Asif Ansari Raj.Deka and Anders Thapper elucidate mono- di and tri-radicals based on contorted polyaromatics functionalized with phosphaalkenes. Congratulations 🎉 🎉 Angewandte Chemie onlinelibrary.wiley.com/doi/10.1002/an…

Latest work from our groups- led by Gargi kundu and duly supported by Debjit/ Soumya Ranjan Dash, Rajesh Gonnade & others -now out DaltonTransactions as part of a themed collection on Main Group Compounds in Materials and Catalysis. Thanks CSIR-National Chemical Laboratory & SERB pubs.rsc.org/en/content/art…

dx.doi.org/10.1021/jacs.4… おもしろ単離論文

Hyped to share our last efforts on main group C=P photoswitches💡 where we explore the mechanism of their isomerization and can observe experimentally the isomerization of symmetrical molecules via NMR🧲! 🥳 Orthaber Lab Raj.Deka SMC Program onlinelibrary.wiley.com/doi/10.1002/an…

Latest paper on "Main group meets photochemistry" by Toma Bhowmick, Jorn Steen et al. Another mysterious phosphaalkene switch... Collab with the Stefano Crespi group. …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ch…

Molecular catalysts and their potential role in green hydrogen sector: A review Led by Suhana Karim in collaboration with Akshai Kumar ACS Catalysis Centre for Climate Studies, IIT Bombay Department of Chemistry, IIT Bombay pubs.acs.org/doi/10.1021/ac…

Just out, reduction of CO2 to MeOH via a Fe(I)-COOH intermediate by Paramita Saha Sk Amanullah pubs.acs.org/doi/10.1021/ja…

Our manuscript “A trimetallic bismuth(I)-based allyl cation” is now online! Check it out: nature.com/articles/s4155… Nature Chemistry Diving into the dark side of Inorg Chem was a pleasure with Cornellab Nils.Not Markus L. F. Neese, M. Van Gastel, and L. Wagner!

A great Start of the year with the first John Callahan of the group!! Synthesis of Heavy Inorganic Rings and their reactivity🧪 Congratulations to Prasenjit Palui and Sangita and all other involved. Thanks to Toni Frontera for the fantastic collaboration. pubs.acs.org/doi/10.1021/ja…

Pd(0)/Pd(II) Electromerism Triggered by Lewis Base Coordination to a Redox-Active Silicon Z-Type Ligand (Lutz Greb and co-workers) @grebgroup Nils Ansmann #openaccess 🔓 onlinelibrary.wiley.com/doi/10.1002/an…

Reversible Metal-Mediated Molecular Switching of a Phosphaethene Polyaromatic Hydrocarbon (Andreas Orthaber Orthaber Lab and co-workers SMC Program) #openaccess 🔓 onlinelibrary.wiley.com/doi/10.1002/ch…

Happy to share our work published in J. Am. Chem. Soc. Thanks to all co-authors Hritwik Haldar Satyabrata Das Katrin Beuthert Stefanie Dehnen Cem B. Yildiz Chris, Haakon. Hritwik’s efforts, Satyabrata’s perseverance are the key players. Incredible collaborations indeed pubs.acs.org/doi/abs/10.102…

doi.org/10.1021/acs.or… Happy to share our work on multiple triazaphospholes hosted on C2 and C3 symmetric platforms using statically encumbered oligo-azides. Done in collaboration with Christian Mueller, Freie Universität. Congratulations to all co-authors doi.org/10.1021/acs.or…

New Class of Carbon-Centered Diradicals Discovered Monosubstituted carbon atom stabilized by a phosphine shows a triplet ground state (work published in Angewandte Chemie) chemistryviews.org/new-class-of-c…

Happy to share my final work from IISER TVM. Special thanks and congratulations to Annabel Benny to be part of this work.

#ICMGSC2025 Prof. Andreas Orthaber from Uppsala University described the highly interesting role of phosphorus moieties in the modulation of the electronic structure of poly aromatic hydrocarbons. Orthaber Lab School of Chemistry IISER TVM Royal Society of Chemistry DaltonTransactions

Axial Carbonate-Bridged Dy2 Complexes Having Rigid N3O2 Equatorial Planes: Stepwise Boosting and Tuning of the Zero-Field SMM Behavior pubs.acs.org/doi/10.1021/ac…

Together with Müller Group Berlin we elucidated the molecular structure of "naked" cyclo-P5- in the crystal! Special thanks to Mirjam and Prof. Corzilius Universität Rostock for their help with 31P ssNMR studies. Read our Angewandte Chemie commuinaction here: onlinelibrary.wiley.com/doi/abs/10.100…

Our new article in Angewandte Chemie is about pushing the limits of organometallic redox chemistry onlinelibrary.wiley.com/doi/10.1002/an…