Coordination Chemistry Meets Boron Helices: Cationic Double-Stranded Diborahelicates and Bora[7]helicenes with Multicolor Emission (J. Am. Chem. Soc.): pubs.acs.org/doi/full/10.10… (Robert J. Gilliard, Jr., Gilliard Group, Heechan Kim).

Coordination Chemistry Meets Boron Helices: Cationic Double-Stranded Diborahelicates and Bora[7]helicenes with Multicolor Emission | Journal of the American Chemical Society Massachusetts Institute of Technology (MIT) Robert J. Gilliard, Jr. MIT Chemistry Gilliard Group pubs.acs.org/doi/10.1021/ja…

For #FluorescenceFriday we share Heechan Kim's new work in J. Am. Chem. Soc. on cationic boron helicates and helicenes! 🔥🔥🔥 #luminescence #boron #chiral #maingroup pubs.acs.org/doi/10.1021/ja…

MIT Chemistry Seminar by Prof. Eli Zysman-Colman (Eli Zysman-Colman) hosted by Gilliard Group: "Design of multiresonance thermally activated delayed fluorescence materials for high-performance organic light-emitting diodes"

We were happy to have Dana Hicks, undergraduate researcher from Macalester College, in our labs this summer as an MSRP intern! oge.mit.edu/msrp/

After our 2025 Gilliard Group Research Retreat where we discussed our research plans for the academic year, we had a nice dinner at Lucca Restaurant!

Our manuscript, led by Nathan Frey, on harnessing substituent and aggregation-induced effects for color-tunable CDP-borafluorenium ions is now online J. Mater. Chem. family C! #maingroup #boron #photophysics Gilliard Group pubs.rsc.org/en/content/art…

Harnessing Substituent and Aggregation-Induced Effects for Color-Tunable Emission in Borafluorenium Ions (Robert J. Gilliard, Jr., Gilliard Group): pubs.rsc.org/en/content/art… (J. Mater. Chem. family).

Our manuscript on the first isolable paramagnetic boron tetraradical is now online J. Am. Chem. Soc. (pubs.acs.org/doi/full/10.10…)! Heechan Kim designed and synthesized an unusual B-PAH tetraradical with tetraphenylethene-linked boraphenanthrene-type units! #maingroup

A Persistent Boron Tetraradical with Tetraphenylethene-Linked Boraphenanthrene-Type Units (J. Am. Chem. Soc.): pubs.acs.org/doi/full/10.10… (Heechan Kim, Robert J. Gilliard, Jr., Gilliard Group).

A Persistent Boron Tetraradical with Tetraphenylethene-Linked Boraphenanthrene-Type Units | Journal of the American Chemical Society UW-Madison Chemistry La Trobe University MIT Chemistry pubs.acs.org/doi/10.1021/ja…

Our manuscript detailing the impact of carbene ligands on diazoboranes is now online in J. Am. Chem. Soc. (pubs.acs.org/doi/full/10.10…)! Chonghe contributes a comprehensive guide covering the synthesis, properties, and reactivity of 8 diazoboranes. Cummins Lab Gilliard Group #maingroup

Impact of Carbene Ligands on the Properties and Reactivity of Diazoboranes (Cummins Lab, Gilliard Group, Robert J. Gilliard, Jr.): pubs.acs.org/doi/full/10.10… (J. Am. Chem. Soc.).

Our manuscript introducing ion-pair assembly in CDC-borenium ions as a method to unlock red to near-infrared luminescence is now published in Nature Chemistry (nature.com/articles/s4155…)! Chunlin shows that counteranion modulation directs solid-state emission! #maingroup

Check out Chun-Lin's (Chun-Lin Deng) new paper in Nature Chemistry (nature.com/articles/s4155…)!🔥🔦⚡️"Unlocking red-to-near-infrared luminescence via ion-pair assembly in carbodicarbene borenium ions" #solidstate #fluorescence #maingroup #realtimechem #boron

Researchers in the Gilliard Lab have designed a new type of fluorescent molecule that they hope could be used for applications such as generating clearer images of tumors. chemistry.mit.edu/chemistry-news…

Unlocking red-to-near-infrared luminescence via ion-pair assembly in carbodicarbene borenium ions (Nature Chemistry): nature.com/articles/s4155… (Robert J. Gilliard, Jr., Gilliard Group).

Congratulations to Nathan Frey on a successful PhD defense MIT Chemistry! He will be an Air Force Science & Technology Postdoctoral Fellow in the AFRL Materials and Manufacturing Directorate! #maingroup Gilliard Group

We are happy to host Prof. Jäkle!!!