In case you missed it: 'Diamidocarbene-derived palladium and nickel–sulfur clusters' by Minji Lee, Hyunju Noh & Youngsuk Kim pubs.rsc.org/en/content/art…

Activation of Strong π–Acids at [Fe4S4]+ Clusters Enabled by a Noncanonical Electronic Structure | Journal of the American Chemical Society Massachusetts Institute of Technology (MIT) MIT Chemistry #Activation #Strong #Pi #Acids #Fe #Clusters #Noncanonical #Electronic #Structure pubs.acs.org/doi/10.1021/ja…

happy to share our group's first submission/publication in Nature Communications on the isolation of a carbene-supported triphosphorus anion. We had an excellent peer review experience! nature.com/articles/s4146…

Lithium Anionic Dicarbenes or Acetylides: What is in the Name? (Rajendra S. Ghadwal and co-workers) Ghadwal Group #AngewandteVIP #openaccess 🔓 onlinelibrary.wiley.com/doi/10.1002/an…

The Outstanding Ambiphilicity of Trialkylstibines among Trialkylpnictines: Power for Stepwise Deoxygenation and N–N Coupling of Nitroarenes | Journal of the American Chemical Society SiChuan University pubs.acs.org/doi/10.1021/ja…

Reactions of R3PNNPR3 species with Boranes: Classical Adducts, FLPs and Radical Cations (Angewandte Chemie): onlinelibrary.wiley.com/doi/10.1002/an… (@FLPchemist).

Link: pubs.acs.org/doi/full/10.10…

Are pyridinylidenes isolable? Here is a crystalline annelated version!! Huge congratulations to @Jachu25 Rodolphe Jazzar for the remarkable work, and my mentee Levan for crystallizing this unprecedented species! #proudmentor pubs.acs.org/doi/10.1021/ja…

A Crystalline Annelated Pyridin-1-ylidene and Its Isomerization into a Pyridin-3-ylidene | Journal of the American Chemical Society UCSD Chem Biochem UC San Diego UNI_Rennes pubs.acs.org/doi/10.1021/ja…

Isolated carbon(I) species featuring a carbone cation radical nature.com/articles/s4416…

Dominik Munz, Jiaxiang Chu & teams report the isolation of ketene in three oxidation states, as well as reactivity studies of isolated ketene radical anions and radical cations • onlinelibrary.wiley.com/doi/10.1002/an…

Air- and Water-Stable Sulfide Radical Cations Supported by Cyclic (Alkyl)(amino)carbenes | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

Excited to share our group's new paper. Thanks to all involved.

Our latest contribution to #OpenShell chemistry from Ghadwal Group — Terphenyl Radicals and Anions: Tuning Stability and Redox Properties via Substituent Patterning — now published in Angewandte Chemie! Thanks to DFG public | @[email protected] for the support! onlinelibrary.wiley.com/doi/10.1002/an…

Ghadwal Group demonstrate the impact of C2-terphenyl substitution patterns (p-terphenyl vs. m-terphenyl) on the redox behavior and stability of radicals and anions derived from N-heterocyclic carbenes #NHC #openaccess 🔓 onlinelibrary.wiley.com/doi/10.1002/an…

Back in 2020, soon after I had isolated the Fe-S cluster terminal imido complex, Dan remarked “I wonder what happens if you oxidize it.” Five years later, we finally have the answer: pubs.acs.org/doi/10.1021/ja…

Our work on the reaction of an NHC with carbon suboxide is out in Chemical Science. Thanks to PhD grad Tanner George for his persistence and attention to detail on this project, collaborator Erin Johnson (Dalhousie), and NSERC / CRSNG for funding. pubs.rsc.org/en/content/art…

Crystalline Plumbynes | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

It is my great pleasure to share our group’s publication in Inorganic Chemistry Frontiers (pubs.rsc.org/en/content/art…). We compared the reactivity of two mixed-valence bimetallic copper complexes. Stay tuned for the transition bimetallic complexes!

Sourav's work on direct interconversion between bis(borylenes) and diborenes is now published in J. Am. Chem. Soc. − give it a read. Many thanks to all contributors!