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Ayesha and Manjur's paper on dearomative borylation of indoles using our strong Lewis acid is now online in DaltonTransactions. Check it out here: pubs.rsc.org/en/content/art…

Nice P-Chem by Ahmad Masarwa (Masarwa Lab) Lab!!!

Nice one!!!

One-Pot Total Synthesis of Post-translationally Modified Max Transcription Factor in Seven Consecutive Steps: Unveiling the Crosstalk Between Ser-Phosphorylation and Lys-Acetylation in DNA Binding | Published J Org Chem/Org Lett pubs.acs.org/doi/10.1021/ac… Congratulations to Nithun and Shada!

Beautiful Carborane Chemistry by The Ye Group!!!

Very cool!! Congrats Laszlo Kurti team!!!

Redox shuttling at silicon... JT's recent work demonstrating reversible Si(II)/Si(IV) redox shuttling via reductive ligand migration is just out in Angewandte Chemie Oxford Chemistry doi.org/10.1002/anie.2…

Corina Stoian's newest contribution: Oxidative Addition of Diaryldichalcogenides to the Diferrocenylphosphenium Ion: Synthesis, Structure and Organocatalytic Activity - now published in Chemical Communications pubs.rsc.org/en/content/art…

This is cool!

Christoph's paper on an exptal and computational study of the 1st cmpds with Be-N and Be-O triple bond character is now out in J. Am. Chem. Soc.. Great (and essential) 1st collab. outing with David J. D. Wilson La Trobe Institute for Molecular Science. #ozchem Humboldt-Stiftung AFOSR Monash Chemistry tinyurl.com/7hmzzzcz

K and Sr join forces in N2 reduction: We describe the looooong road to Sr-N2 complexes. So reactive!!! Converts Teflon within minutes in a soluble form of K+F- 长欣 赵 doi.org/10.1002/anie.2…

Our latest paper is now out in J. Am. Chem. Soc. ! We unveil a new strategy to access elusive free oxoboranes—highly reactive species—via bridged boranoanthracenes and aromatization-driven extrusion. Congratulations to the team! pubs.acs.org/doi/10.1021/ja…

Our manuscript on the first diboron-incorporated indenofluorenes is online in J. Am. Chem. Soc.! Eric and coworkers report pentacyclic neutral, diradical, radical anion, and dianion ring systems w/18, 20, 21, and 22π electrons! #maingroup #boron #paramagnetic pubs.acs.org/doi/full/10.10…

Our (Gilliard Group, Cummins Lab) manuscript on the generation of transient, sterically unhindered multiply bonded boron species is now published in Chemical Science! Chonghe reports an array of new boron heterocycles! #maingroup #boron pubs.rsc.org/en/content/art…

LOW-VALENT Si, Ge, Sn, Pb: HOW LOW CAN WE GO??? Hydrocarbon-soluble Mg(0) reduces Si all the way to Si(4-). Unfortunately not stable and decomposing to the HSi(3-) anion. However, Sn(4-) is stable and functions as 4-fold Nu or 8e reducing agent. Preprint: shorturl.at/4mH0O

Very interesting and thorough study of the three structurally constrained pnictogen centers (P, Sb, and Bi) in a redox-active ligand. Congrats to the team!!

Our manuscript on unlocking the ambiphilicity of boryl anions is now published in J. Am. Chem. Soc. (pubs.acs.org/doi/full/10.10…)! Chonghe, Junyi, Xibao, and coworkers report the synthesis and reactivity of the first anionic diazoborane! #maingroup Cummins Lab Gilliard Group

Wow, cool

New preprint alert! Our latest work delves into the exploration of forging Boron-Tetrel bonds in carboranes. If you're intrigued by salt melt reactions exceeding 300°C and the fascinating realm of main group elements, you should check this out: doi.org/10.26434/chemr…