Light- and Heat-Responsive Frustrated Lewis Pair Enables On-Demand Fixation of Ethylene | Journal of the American Chemical Society The University of Osaka 大阪大学 pubs.acs.org/doi/10.1021/ja…

#TotalSynthesis of (−)-Illisimonin A Enabled by Pattern Recognition and Olefin Transposition by Bo Xu, Ziyao Zhang, and Mingji Dai at Emory Chemistry in J. Am. Chem. Soc. pubs.acs.org/doi/10.1021/ja…

Check out our illisimonin A total synthesis J. Am. Chem. Soc. and find out how we make an olefin dance around the ring! Total Synthesis of (−)-Illisimonin A Enabled by Pattern Recognition and Olefin Transposition | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

A Catalytic Asymmetric Intramolecular [4 + 1]-Cycloaddition for the Total Synthesis of Terpene Alkaloid Natural Products | Journal of the American Chemical Society Uyeda Lab Research at Purdue Total Synthesis and Methodology Highlights pubs.acs.org/doi/10.1021/ja…

nature.com/articles/s4146… Photoinduced Thia-Baeyer Villiger oxidation. Found this gem while doing some lit searches.

Ni-Catalyzed Reductive Ring Contraction via Desulfurative Cross-Coupling | Journal of the American Chemical Society Total Synthesis and Methodology Highlights Harvard University Harvard Chemistry pubs.acs.org/doi/10.1021/ja…

My lab’s next paper is out in JACS! Our electrode-orthogonal self-assembled layers can "self-heal" after degradation -- the key is a dynamic linkage we can molecularly tune! Hats off to Nico! pubs.acs.org/doi/full/10.10…

From Alex in the Chirik Group . Site-selective Co-catalyzed borylation of electron-rich arenes, now out in J. Am. Chem. Soc.. pubs.acs.org/doi/full/10.10…

Direct N–SF5 and N–SF4CF3 Bond Formation through Strain-Release Functionalization of 3-Substituted [1.1.0]Azabicyclobutanes | Journal of the American Chemical Society Cody Ross Pitts UC Davis pubs.acs.org/doi/10.1021/ja…

Remote-Markovnikov Hydrobromination and Hydrochlorination of Allyl Carboxylates via Dual Photoredox/Cobalt Catalysis pubs.acs.org/doi/10.1021/ja…

Clever use of Ramberg-Backlund!

Our neocucurbol C total synthesis is out J. Am. Chem. Soc.! Total Synthesis of (−)-Neocucurbol C Enabled by Pattern Recognition and MHAT Cyclization | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

#TotalSynthesis of (−)-Neocucurbol C Enabled by Pattern Recognition and MHAT Cyclization by Li-Ping Zhong, Cyrus Gudeman, Jingsong Zhen (Jingsong Zhen), Oshani A. Wanasinghe, Jacob Hellmig, Michael J. E. Collins, John Bacsa, Alexander Adibekian, Mingji Dai at Emory Chemistry in J. Am. Chem. Soc.

Adding to the growing toolbox of aryl azide syntheses: From Shangyu Li on ChemRxiv, Pd-catalyzed coupling of ArBr/ArOTf with NaN3. This reaction is trickier than it looks: as we show, [LPd-N3]2 dimers form with many L's & the pdt can inhibit Pd(0). doi.org/10.26434/chemr…

Arylboration of Cyclic Enones via Cooperative Copper/Palladium Catalysis (J Org Chem/Org Lett): pubs.acs.org/doi/10.1021/ac….

In our total synthesis of psathyrin A fresh J. Am. Chem. Soc., we challenged the MHAT radical chemistry to build four-membered ring and it worked! Total Synthesis of (−)-Psathyrin A Enabled by Radical Cyclization | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

Final version out today in nature : nature.com/articles/s4158… Thanks to the Roberto and Cravatt labs for biological evaluations!

Mechanism of Redox-Neutral Radical Cross Coupling (another fun collaboration with the Blackmond Group), out today in ChemRxiv : chemrxiv.org/engage/chemrxi…

a-F-amines are unstable. Not in Ukraine!