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Check out our journey into s-block bimetallics ChemRxiv! This study spearheaded by Errikos Kounalis shows how restraining two Mg centers in close proximity alters the reactivity of alkylmagnesium complexes - go.shr.lc/3Xg6AGI

Proud to share Vishal's latest work in Chem Catalysis on controlling hydrogen transfer dynamics in alkyne semihydrogenation. We developed an adaptive catalyst for selective production of cis- and trans-alkenes with precise control over reaction mechanisms. sciencedirect.com/science/articl…

Check out these 2 connected preprints ChemRxiv. First synthesis and reactivity shorturl.at/BGL0u and an X-ray spectroscopic study into the metal-metal bonding of dicobalt complexes shorturl.at/kYbju. Great collab with Roel Bienenmann, Arun Asundi and Ritimukta Sarangi!

Hydride as a Leaving Group in Nucleophilic Aromatic Substitution Beauty in simplicity, spaceship-like halfsandwich complex 🛸 Daniel Broere Stanislav Melnikov Baik Group ChemRxiv

[Great News🎉] Thrilled to announce that our latest paper "Direct evidence for a carbon–carbon one-electron σ-bond" is now out in @nature ! Huge congrats to Takuya Takuya SHIMAJIRI , Soki Soki Kawaguchi , and all involved🎉🎊 nature.com/articles/s4158…

Great to see this study led by Roel Bienenmann make it to print! Great example where peer-review strengthened the message! Previously on ChemRxiv, now in ACS Catalysis Mechanistic Investigation into Copper(I) Hydride Catalyzed Formic Acid Dehydrogenation pubs.acs.org/doi/10.1021/ac…

Novel cases of strain-promoted cyclotrimerizations of alkyne CPPs to make pinwheel-like nanostructures are reported in J. Am. Chem. Soc. . CSD Entry XUKQED packs into an interdigitated structure with extensive solvent-filled channels. 🔗 ccdc-info.com/3C4BR79 #FeaturedStructureFriday

Antiaromatic Metallacyclopentatriene Complexes | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/ja…

I'm really happy that my dicobalt work with Daniel Broere has made it into Organometallics! Thanks also to our collaborators Arun Asundi and Ritimukta Sarangi at SLAC! Want to see what the PNNP expanded pincer ligand can do with cobalt? Check it out: doi.org/10.1021/acs.or…

My dear friend and colleague Eva Harsevoort just got her super cool work on closed-loop chemical recycling published in J. Am. Chem. Soc. Gefeliciteerd ♻️ pubs.acs.org/doi/10.1021/ja…

To wrap up a great year: how to use M-M bonds to passivate a catalyst and tune selectivity: "Reversible Bimetallic Inhibition to Modulate Selectivity During Catalysis" | J. Am. Chem. Soc. 🥳🥳🥳 Emmanuel @Pita_chem Juan José Moreno Jesus Rangel G and #MartaR pubs.acs.org/doi/10.1021/ja…

A unique [2]catenane comprising two intertwined, globally aromatic octaphyrinoid rings, showing through-space electronic coupling and tunable aromaticity. A preprint of this collaborative work is now available on ChemRxiv: chemrxiv.org/engage/chemrxi…

Our latest SMOM paper now out in J. Am. Chem. Soc.. Single-crystal to single-crystal methane and ethane activation at an Ir-pincer complex. Molecular solid-state reactivity, neutron-diffraction, SSNMR, Periodic-DFT & inverse isotope effects. With The Macgregor Group pubs.acs.org/doi/10.1021/ja…

Congrats to Xin-Feng, Rui, Walter and Chaopeng! We documented the isolation of keteniminyl anions [RC=C=NR]-, now featured in Chem!

Regiodivergent Alkylation of Pyridines: Alkyllithium Clusters Direct Chemical Reactivity | Journal of the American Chemical Society KAISTPR KAIST Chemistry POSTECH IBS_media(기초과학연구원) Total Synthesis and Methodology Highlights pubs.acs.org/doi/10.1021/ja…

Our nitrene insertion into boranes is finally published in Chemical Science. Think about replacing your C-C bonds with fancy B-N bonds :) doi.org/10.1039/D5SC00…

Catalytic methane functionalization and all it takes is... beryllium! We also compare the mechanisms of methane beryllation and borylation to reveal why Be finds it so easy J. Am. Chem. Soc. Aldridge Group pubs.acs.org/doi/10.1021/ja…

This was a great #N3C for our group: Fantastic talks by Stanislav Melnikov and Luuk Stringer , posters by Rik Multem and Pablo García Porta. Cherry on the cake: Winning the N3C award, recognizing the cumulative efforts of all (former) group members! 🎉

Check out our first steps into the main group ChemRxiv ! Pioneered by Errikos Kounalis and in collab with Marc-Etienne Moret | @[email protected] An N-Heterocyclic Germylene with a Versatile Metal-Binding Pocket: Insights into Heterodinuclear Bonding and Reactivity | ChemRxiv - go.shr.lc/41X9QI5

Polymer friends! 🥂 My first PhD paper is out now in @ACS_Macromol! We explored how subtle changes in the monomers structure GREATLY influences their polymerisation behaviour and discovered some very rare reactivity in the process. pubs.acs.org/doi/10.1021/ac… #Polymer #chemtwitter